The [Ti12Nb6O44]10- ion - A new type of polyoxometalate structure

C. André Ohlin; Eric M. Villa; James C. Fettinger; William H. Casey

doi:10.1002/anie.200801883

The [Ti₁₂Nb₆O₄₄]^10- ion - A new type of polyoxometalate structure

C. André Ohlin, Eric M. Villa, James C. Fettinger, William H. Casey

Research output: Contribution to journal › Article › peer-review

88 Scopus citations

Abstract

An extraordinarily useful cluster to detail reaction pathways in water might have been obtained in form of [N-(CH₃)₄] ₁₀[Ti₁₂Nb₆O₄₄], a polyoxometalate with a central cavity. This compound is soluble in a range of solvents and has been characterized by ESI mass spectrometry and X-ray crystallography (see picture; [1]=[Ti₁₂Nb₆O₄₄]^10-). (Graph Presented)

Original language	English (US)
Pages (from-to)	5634-5636
Number of pages	3
Journal	Angewandte Chemie - International Edition
Volume	47
Issue number	30
DOIs	https://doi.org/10.1002/anie.200801883
State	Published - Jul 14 2008
Externally published	Yes

All Science Journal Classification (ASJC) codes

Catalysis
Chemistry(all)

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10.1002/anie.200801883

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abstract = "An extraordinarily useful cluster to detail reaction pathways in water might have been obtained in form of [N-(CH3)4] 10[Ti12Nb6O44], a polyoxometalate with a central cavity. This compound is soluble in a range of solvents and has been characterized by ESI mass spectrometry and X-ray crystallography (see picture; [1]=[Ti12Nb6O44]10-). (Graph Presented)",

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AU - Ohlin, C. André

AU - Villa, Eric M.

AU - Fettinger, James C.

AU - Casey, William H.

PY - 2008/7/14

Y1 - 2008/7/14

N2 - An extraordinarily useful cluster to detail reaction pathways in water might have been obtained in form of [N-(CH3)4] 10[Ti12Nb6O44], a polyoxometalate with a central cavity. This compound is soluble in a range of solvents and has been characterized by ESI mass spectrometry and X-ray crystallography (see picture; [1]=[Ti12Nb6O44]10-). (Graph Presented)

AB - An extraordinarily useful cluster to detail reaction pathways in water might have been obtained in form of [N-(CH3)4] 10[Ti12Nb6O44], a polyoxometalate with a central cavity. This compound is soluble in a range of solvents and has been characterized by ESI mass spectrometry and X-ray crystallography (see picture; [1]=[Ti12Nb6O44]10-). (Graph Presented)

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The [Ti₁₂Nb₆O₄₄]^10- ion - A new type of polyoxometalate structure

Abstract

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