1,6-addition of organocopper reagents to 3-ethynyl-2-methyl-2-cyclopentenone

Martin Hulce

doi:10.1016/S0040-4039(00)82207-8

1,6-addition of organocopper reagents to 3-ethynyl-2-methyl-2-cyclopentenone

Martin Hulce

Research output: Contribution to journal › Article › peer-review

17 Scopus citations

Abstract

Enynone 1 undergoes facile 1,6-addition of organocopper reagents to yield allenyl enols 5 which stereoselectively isomerize to Z-dienones 2.

Original language	English (US)
Pages (from-to)	5851-5854
Number of pages	4
Journal	Tetrahedron Letters
Volume	29
Issue number	46
DOIs	https://doi.org/10.1016/S0040-4039(00)82207-8
State	Published - 1988
Externally published	Yes

All Science Journal Classification (ASJC) codes

Biochemistry
Drug Discovery
Organic Chemistry

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10.1016/S0040-4039(00)82207-8

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@article{483e7b20e60d4253b992e955817b5cb4,

title = "1,6-addition of organocopper reagents to 3-ethynyl-2-methyl-2-cyclopentenone",

abstract = "Enynone 1 undergoes facile 1,6-addition of organocopper reagents to yield allenyl enols 5 which stereoselectively isomerize to Z-dienones 2.",

author = "Martin Hulce",

note = "Funding Information: Acknowledgement, The work was supported by the Donors of the Petroleum Research Fund, administered by the American Chemical Society, and by American Cancer Society Institutional Research Grant #IN-147F. MD Cancer Program/University of MD.",

year = "1988",

doi = "10.1016/S0040-4039(00)82207-8",

language = "English (US)",

volume = "29",

pages = "5851--5854",

journal = "Tetrahedron Letters",

issn = "0040-4039",

publisher = "Elsevier Limited",

number = "46",

}

TY - JOUR

T1 - 1,6-addition of organocopper reagents to 3-ethynyl-2-methyl-2-cyclopentenone

AU - Hulce, Martin

N1 - Funding Information: Acknowledgement, The work was supported by the Donors of the Petroleum Research Fund, administered by the American Chemical Society, and by American Cancer Society Institutional Research Grant #IN-147F. MD Cancer Program/University of MD.

PY - 1988

Y1 - 1988

N2 - Enynone 1 undergoes facile 1,6-addition of organocopper reagents to yield allenyl enols 5 which stereoselectively isomerize to Z-dienones 2.

AB - Enynone 1 undergoes facile 1,6-addition of organocopper reagents to yield allenyl enols 5 which stereoselectively isomerize to Z-dienones 2.

UR - http://www.scopus.com/inward/record.url?scp=0345818042&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0345818042&partnerID=8YFLogxK

U2 - 10.1016/S0040-4039(00)82207-8

DO - 10.1016/S0040-4039(00)82207-8

M3 - Article

AN - SCOPUS:0345818042

SN - 0040-4039

VL - 29

SP - 5851

EP - 5854

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 46

ER -

1,6-addition of organocopper reagents to 3-ethynyl-2-methyl-2-cyclopentenone

Abstract

All Science Journal Classification (ASJC) codes

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